A computer simulation study of natural silicate melts. Part I: Low pressure properties     

Bertrand Guillot  Nicolas Sator 《Geochimica et cosmochimica acta》2007,71(5):1249-1265

In implementing into a molecular dynamics simulation code a simple interionic potential developed to describe the nine component system K₂O-Na₂O-CaO-MgO-FeO-Fe₂O₃-Al₂O₃-TiO₂-SiO₂ (KNCMFATS), it has been possible to reproduce satisfactorily a number of thermodynamic, structural and transport properties of a representative set of natural silicate melts. An important conclusion reached in this study is the good transferability of the potential from felsic to ultramafic compositions although this transferability becomes less accurate with high silica contents (rhyolitic composition and beyond) and with very iron-rich silicates (e.g. fayalite). A key feature of the simulation is to make the link between macroscopic properties of the melt and its microscopic structure and dynamics. We thus obtain a relationship between the molar volume of the melt, the number of network modifiers and the oxygen coordination number. The simulation also allows one to quantify the coordination environment around the cations as function of the melt composition. Furthermore, the electrical conductivity of the high temperature liquid is investigated.  相似文献   

Analysis of rock drainage and cooling experiments for underground cryogenic LNG storage     

Sung-Soo Cha  Kang-Kun Lee  Gwang-Ok Bae  Dae-Hyuck Lee  Nicolas Gatelier 《Engineering Geology》2007,93(3-4):117-129

Hydrogeological monitoring was conducted around a pilot cavern for underground cryogenic LNG (Liquefied Natural Gas) storage. The monitoring was mainly focused on the operation of a drainage and recharge system. After the operation of the drainage system commenced, the drainage rate decreased rapidly in the initial stages and then decreased gradually. Hydrogeological monitoring revealed that the rock drainage system operated effectively. During drainage, the water table was maintained below the cavern roof. The recharge for ice-ring formation was performed in two phases. The first phase involved the cessation of pumping in downward-drainage holes and the second involved the closure of upward boreholes. Since the water table was maintained below the cavern roof, artificial recharge was planned at first. However, it was not implemented due to heavy rainfall in the recharge stage. On the basis of hydrogeological monitoring and hydraulic tests, it was found that the fractures above the roof and on the right wall of the pilot cavern mainly affected seepage into the cavern and thermal variation due to the storage of liquid nitrogen. Thermal variation was examined by the thermometers installed around the pilot cavern. The cooling and thawing processes reveal the characteristics of thermal distribution in the rock and the 0 °C isotherm. The cooling phase lasted for six months, and the 0 °C isotherm progressed in time after the injection of liquid nitrogen into the cavern. The isotherm propagated up to about 4 m from the floor and the sidewall of the cavern and about 3 m from the cavern roof. The cooling rate of the rock mass above the cavern roof was lower than that of the other cavern sides due to the gaseous space in the upper part of the containment. The fractures were analyzed and considered for thermal modeling. A two-dimensional finite element analysis was performed to compare the field monitoring at the pilot cavern. The numerical modeling shows the distance between the ice ring and heat transfer pattern of the fractures around the pilot cavern. The propagation of the measured and calculated 0 °C isotherm reveals that the water-conveying joint on the right wall might affect thermal propagation through a thermal pipe.  相似文献   

On the Correlation between Convective Plume Updrafts and Downdrafts,Lidar Reflectivity and Depolarization Ratio     

Fabien Gibert  Juan Cuesta  Jun-Ichi Yano  Nicolas Arnault  Pierre H. Flamant 《Boundary-Layer Meteorology》2007,125(3):553-573

We question the correlation between vertical velocity (w) on the one hand and the occurrence of convective plumes in lidar reflectivity (i.e. range corrected backscatter signal Pz ²) and depolarization ratio (Δ) on the other hand in the convective boundary layer (CBL). Thermal vertical motion is directly investigated using vertical velocities measured by a ground-based Doppler lidar operating at 2 μm. This lidar provides also simultaneous measurements of lidar reflectivity. In addition, a second lidar 200 m away provides reflectivities at 0.53 and 1 μm and depolarization ratio at 0.53 μm. The time series from the two lidars are analyzed in terms of linear correlation coefficient (ρ). The main result is that the plume-like structures provided by lidar reflectivity within the CBL as well as the CBL height are not a clear signature of updrafts. It is shown that the lidar reflectivity within the CBL is frequently anti-correlated (ρ (w, Pz ² )) with the vertical velocity. On the contrary, the correlation coefficient between the depolarization ratio and the vertical velocity ρ (w, Δ ) is always positive, showing that the depolarization ratio is a fair tracer of updrafts. The importance of relative humidity on the correlation coefficient is discussed. An erratum to this article can be found at  相似文献   

Climate extremes in Loess of China coupled with the strength of deep-water formation in the North Atlantic   总被引：1，自引：0，他引：1  

Zhengtang Guo  Tungsheng Liu  Nicolas Fedoroff  Lanying Wei  Zhongli Ding  Naiqin Wu  Huoyuan Lu  Wenying Jiang  Zhisheng An 《Global and Planetary Change》1998,18(3-4)

The loess-paleosol sequences of the last 1.2 Ma in China have recorded two kinds of climate extremes: the strongly developed S4, S5-1 and S5-3 soils (corresponding to the marine δ¹⁸O stages 11, 13, and 15, respectively) as evidence of three episodes of great warmth and two coarse-grained loess units (L9 and L15, corresponding to the marine δ¹⁸O stages 22, 23, 24 and 38, respectively) which indicate severest glacial conditions. The climatic and geographical significance of these events are still unclear, and their cause remains a puzzle.Paleopedological, geochemical and magnetic susceptibility data from three loess sections (Xifeng, Changwu and Weinan) suggest that the S4, S5-1 and S5-3 soils were formed under sub-tropical semi-humid climates with a tentatively estimated mean annual temperature (MAT) of at least 4–6°C higher and a mean annual precipitation (MAP) of 200–300 mm higher than for the present-day, indicating a much strengthened summer monsoon. The annual rainfall was particularly accentuated for the southern-most part of the Loess Plateau, suggesting that the monsoon rain belt (the contact of the monsoonal northward warm-humid air mass with the dry-cold southward one) might have stood at the southern part of the Plateau for a relatively long period each year. The loess units L9 and L15 were deposited under semi-desertic environments with a tentatively estimated MAT and MAP of only about 1.5–3°C and 150–250 mm, indicating a much strengthened winter monsoon, and that the summer monsoon front could rarely penetrate into the Loess Plateau region.Correlation with marine carbon isotope records suggests that these climate extremes have large regional, even global, significance rather than being local phenomena in China. They match the periods with greatest/smallest Atlantic–Pacific δ¹³C gradients, respectively, indicating their relationships with the strength of Deep Water (NADW) production in the North Atlantic. These results suggest that the monsoon climate in the Loess Plateau region was significantly linked with the North Atlantic thermohaline circulation on timescales of 10⁴ years.  相似文献   

From subduction to transform motion: a seabeam survey of the Hellenic trench system     

Xavier Le Pichon  Jacques Angelier  Jean Aubouin  Nicolas Lyberis  Serge Monti  Vincent Renard  Henri Got  Ken Hsu¨  Yossi Mart  Jean Mascle  Drummond Matthews  Dimitri Mitropoulos  Pandelis Tsoflias  Georges Chronis 《Earth and Planetary Science Letters》1979,44(3):441-450

Preliminary results of a multi-narrow beam survey of the Hellenic trench system, in the Eastern Mediterranean, are presented. The southwestern Ionian branch is divided in small basins, partly filled with Pleistocene sediments. The morphology suggests that the basins are deformed by a compressional stress acting roughly perpendicularly to the trench along N50°E. This direction is the direction of the regional slip vector of the shallow thrust-type earthquakes. The structure of the southeastern Pliny-Strabo branch is quite different. Narrow en-e´chelon slots, oriented N40°E, have been mapped within the main troughs oriented N60°E. The regional earthquake slip vector is also oriented along N40°E. We conclude that the Hellenic trench system is an active subduction system, dominated by thrust along the Ionian branch and by transform motion along the Pliny-Strabo branch.  相似文献   

Flow in upper-mantle rocks: Some geophysical and geodynamic consequences   总被引：1，自引：0，他引：1  

Adolphe Nicolas 《Tectonophysics》1976,32(1-2)

Flow mechanisms effective in the upper mantle and some of the parameters of the creep equation are determined from the study of peridotites from basalt and kimberlite xenoliths and alpine-type massifs. Creep controlled by dislocation climb, as inferred by Weertman, is the dominant mechanism. Evidence for superplastic flow is found in the deepest kimberlite xenoliths. Flow in the alpine-type massifs is ascribed either to intrusion in the crust when continental plates collide (lherzolite massifs) or to sea-floor spreading (harzburgite massifs included in ophiolites). The consideration of textures, crystal substructures and preferred orientations connected with P,T equilibrium conditions derived from pyroxenes, helps in deciphering the large-scale structure and flow of peridotites in the crust and in the mantle down to 200 km. For the first 150 km, the representative structures are those of the basalt xenoliths and the kimberlite xenoliths with a coarsegrained texture. They have many features in common and probably represent a static lithosphere with, in basalt xenoliths, possible evidence for the transition to the shear flowing asthenosphere. The porphyroclastic and mosaic-textured xenoliths, in kimberlites equilibrated at depth between 150 and 200 km and a few more superficial basalt xenoliths, reflect a much larger strain rate and applied stress and might be connected to vertical instabilities also responsible for magma genesis.  相似文献   

Mass‐dependent fractionation of nickel isotopes in meteoritic metal     

David L. COOK  Meenakshi WADHWA  Robert N. CLAYTON  Nicolas DAUPHAS  Philip E. JANNEY  Andrew M. DAVIS 《Meteoritics & planetary science》2007,42(12):2067-2077

Abstract— We measured nickel isotopes via multicollector inductively coupled plasma mass spectrometry (MC‐ICPMS) in the bulk metal from 36 meteorites, including chondrites, pallasites, and irons (magmatic and non‐magmatic). The Ni isotopes in these meteorites are mass fractionated; the fractionation spans an overall range of ～0.4‰ amu^?1. The ranges of Ni isotopic compositions (relative to the SRM 986 Ni isotopic standard) in metal from iron meteorites (～0.0 to ～0.3‰ amu^?1) and chondrites (～0.0 to ～0.2‰ amu^?1) are similar, whereas the range in pallasite metal (～–0.1 to 0.0‰ amu^?1) appears distinct. The fractionation of Ni isotopes within a suite of fourteen IIIAB irons (～0.0 to ～0.3‰ amu^?1) spans the entire range measured in all magmatic irons. However, the degree of Ni isotopic fractionation in these samples does not correlate with their Ni content, suggesting that core crystallization did not fractionate Ni isotopes in a systematic way. We also measured the Ni and Fe isotopes in adjacent kamacite and taenite from the Toluca IAB iron meteorite. Nickel isotopes show clearly resolvable fractionation between these two phases; kamacite is heavier relative to taenite by ～0.4‰ amu^?1. In contrast, the Fe isotopes do not show a resolvable fractionation between kamacite and taenite. The observed isotopic compositions of kamacite and taenite can be understood in terms of kinetic fractionation due to diffusion of Ni during cooling of the Fe‐Ni alloy and the development of the Widmanstätten pattern.  相似文献   

Sedimentary evidence of deglacial megafloods in the northern Gulf of Mexico (Pigmy Basin)     

Jean Carlos Montero-Serrano  Viviane Bout-Roumazeilles  Nicolas Tribovillard  Thomas Sionneau  Armelle Riboulleau  Aloys Bory  Benjamin Flower 《Quaternary Science Reviews》2009,28(27-28):3333-3347

Cored sediments from the Pigmy Basin, northern Gulf of Mexico, were analyzed in order to better constrain late deglacial and early Holocene paleoenvironmental and sedimentary changes in response to North American climate evolution. Mineralogical and geochemical proxies indicate the succession of two sedimentary regimes: dominantly detrital during the deglaciation (15–12.9 cal ka BP) whereas biogenic contribution relatively increased later on during the Younger Dryas and early Holocene (12.9 and 10 cal ka BP). Geochemical data reveal that the deglacial record mainly reflects variations of terrigenous supply via the Mississippi River rather than modifications of redox conditions in the basin. Specific variations of almost all the parameters measured in this paper are synchronous with the main deglacial meltwater episode (Meltwater Spike) described or modeled in previous marine or continental studies. During this episode, most parameters display “stair-step-like” – pattern variations highlighting three successive steps within the main meltwater flow. Variations in grain-size and clay mineral assemblage recorded in the Pigmy Basin indicate that the erosional regime was very strong on land during the first part of the Meltwater Spike, and then milder, inducing more subtle modifications in the sedimentary regime in this part of the Gulf. Specific geochemical and mineralogical signatures (notably, clay minerals and trace metal geochemistry) pinpoint a dominant origin from NW North America for detrital particles reflecting meltwater outflow from the south-western Laurentide Ice Sheet (LIS) margin during the most intense freshwater discharge. The observed decrease of the sedimentation rate from about 200 to 25 cm/ka at ca 12.9 ka evidenced a drastic decrease of erosional processes during late phase of discharge, consistently with the hypotheses of major reduction of meltwater flow. The major modification at 12.9 cal ka BP is interpreted to result from both modifications of the main Mississippi fluvial regime due to eastward and northward rerouting of meltwater flow at the onset of the Younger Dryas, and the increase of sea-surface temperature linked to insolation. Finally, slight grain-size modifications suggest that some freshwater discharges may have episodically reached the Gulf of Mexico after the Younger Dryas reflecting possible small adjustments of the postglacial hydrological regime.  相似文献   

Recursive algorithms for the computation of the potential harmonic coefficients of a constant density polyhedron   总被引：1，自引：0，他引：1  

Dimitrios Tsoulis  Olivier Jamet  Jérôme Verdun  Nicolas Gonindard 《Journal of Geodesy》2009,83(10):925-942

The gravitational potential of a constant density general polyhedron can be expressed both in terms of a closed analytical expression and as a series expansion involving the corresponding spherical harmonic coefficients. The latter can be obtained from two independent algorithms, which differ not only in their algorithmic architecture but in their efficiency and overall performance, especially when computing the coefficients of higher degree and order. In the present paper a comparative study of all these three approaches is carried out focusing on the numerical implementation of the recursive relations appearing in the two algorithms for the computation of the polyhedral potential harmonic coefficients. The performed numerical investigations show that the linear algorithm proposed by Jamet and Thomas (Proceedings of the second international GOCE user workshop, ‘GOCE, The Geoid and Oceanography’, ESA-ESRIN, Frascati, Italy, 8–10 March 2004, ESA SP-569, 2004), but so far not implemented, achieves a reasonable accuracy at a computational expense that opens to practical applications, for instance in the field of satellite gravimetry/gradiometry interpretation. The convergence behavior of the linear recursion algorithm is studied thoroughly and a computational procedure is proposed that enables the stable computation of potential harmonic coefficients up to degree 60 when referring to an arbitrarily shaped polyhedral body.  相似文献   

Corrigendum to “Climatological mean and decadal change in surface ocean pCO₂, and net sea–air CO₂ flux over the global oceans” [Deep Sea Res. II 56 (2009) 554–577]     

Taro Takahashi  Stewart C. Sutherland  Rik Wanninkhof  Colm Sweeney  Richard A. Feely  David W. Chipman  Burke Hales  Gernot Friederich  Francisco Chavez  Christopher Sabine  Andrew Watson  Dorothee C.E. Bakker  Ute Schuster  Nicolas Metzl  Hisayuki Yoshikawa-Inoue  Masao Ishii  Takashi Midorikawa  Yukihiro Nojiri  Arne Krtzinger  Tobias Steinhoff  Mario Hoppema  Jon Olafsson  Thorarinn S. Arnarson  Bronte Tilbrook  Truls Johannessen  Are Olsen  Richard Bellerby  C.S. Wong  Bruno Delille  N.R. Bates  Hein J.W. de Baar 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(11):2075-2076

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